Researching Photoinduced Molecular Events
Journal Publications
(see below for Patents and Dissertations)
- Claude Bernard -
“The joy of discovery is certainly the liveliest that the mind of man can ever feel”
Artwork by Ella Maru
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Associate Professor Publications
Artwork by Karina Kapusta
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AFRL/UES Research Scientist Publications
I) [Ceramics] Delcamp, J. H.; Martin, K. L.; Posey, N. D.; Acord, K. A.; Thompson, C. M.; Dickerson, M. B. "Preceramic Polymers Grafted to SiO2 Nanoparticles via Metal Coordination Pyrolyzing with High Ceramic Yields: Implications for Aerospace Propulsion and Biomedical Coatings" ACS Appl. Nano Mater. 2023, 6, 3661. [link]
II) [Ceramics] Posey, N. D.; Delcamp, J. H.; Dickerson, M. B. "Preceramic polymer-grafted nanoparticles assembled via ionic complexation" Open Ceramics 2023, 14, 100349. [link]
132) [NIR/SWIR Materials] Saucier, M. A.; Kruse, N. A.; Seidel, B. E.; Hammer, N. I.; Tschumper, G. S.; Delcamp, J. H.; "Shortwave Infrared Absorbing Phospha-RosIndolizine Dye with Peak SWIR Absorption and Emission" Submitted as of May 2024. T12
131) [NIR/SWIR Materials] Meador, W. E.; Saucier, M. A.; Tucker, M. R.; Mobley, A. J.; Parkin, S. R.; Clark, K. M.; Tschumper, G. S.; Delcamp, J. H.; "Extended Shortwave Infrared Absorbing Antiaromatic Fluorenium-Indolizine Chromophores" Submitted as of May 2024. T12
130) [Chromophores & Interfaces] Devdass, A.; Watson, J.; Delcamp, J. H.; Jurss, J. W. "Copper-based Redox Shuttles Supported by Pentadentate Ligands for Dye- Sensitized Solar Cells with High Efficiencies Under Low-Light Conditions" Submitted as of May 2024. T12
129) [Catalysis] Manafe, S. Y.; Le, N.; Lambert, E. C.; Curiac, C.; Nugegoda, D.; Das, S.; Hunt, L. A.; Qu, F.; Whitt, L. M.; Fedin, I.; Hammer, N. I.; Webster, E. C.; Delcamp, J. H.; Papish, E. T. "Sensitized and Self-Sensitized Photocatalytic CO2 Reduction to HCO2– and CO under Visible Light with Ni(II) CNC-Pincer Catalysts" ACS Catal. 2024, 14, 6589. CAT [link]
128) [NIR/SWIR Materials] Saucier, M. A.; Kruse, N. A.; Lewis, T. A.; Hammer, N. I.; Delcamp, J. H. "Switch-on Near Infrared Emission in Albumin Behind Dark Fabric: Toward Application in Forensic Latent Bloodstain Detection" RSC Adv. 2024, 14, 9254. T12 [link]
127) [NIR/SWIR Materials] Meador, W. E.; Lewis, T. A.; Shaik, A. K.; Wijesinghe, K. H.; Yang, B.; Dass, A.; Hammer, N. I.; Delcamp, J. H. "Molecular Engineering of Stabilized Silicon-Rosindolizine Shortwave Infrared Fluorophores" J. Org. Chem. 2024, 89, 2825. T12 [link]
126) [NIR/SWIR Materials] Meador, W. E.; Lin, E. Y.; Lim, I.; Friedman, H. C.; Ndaleh, D.; Shaik, A. K.; Hammer, N. I.; Yang, B.; Caram, J. R.; Sletten, E. M.; Delcamp, J. H. "Silicon-RosIndolizine Fluorophores with Shortwave Infrared Absorption and Emission Profiles Enable in vivo Fluorescence Imaging" Nature Chem. 2024, DOI: 10.1038/s41557-024-01464-6. T12 [link]
125) [NIR/SWIR Materials] Kaur, R.; Kruse, N. A.; Smith, C.; Hammer, N. I.; Delcamp, J. H. "Comparison of Vinyldimethylaniline and Indolizine Donor Groups on Si-Substituted Xanthene Core Shortwave Infrared Fluorophores" ChemPhotoChem 2024, DOI: 10.1002/cptc.202400023. T12 [link]
124) [Chromophores & Interfaces] Kaur, R.; Dalpati, N.; Delcamp, J. H.; Farnum, B. H. "Nickel-Based Two-Electron Redox Shuttle for Dye-Sensitized Solar Cells in Low Light Applications" ACS Appl.Energy Mater. 2024, DOI: 10.1021/acsaem.3c03198. NSC [link]
123) [Strong Photooxidant] Li, Q. Y.; Lambert, E. C.; Kaur, R.; Hammer, N. I.; Delcamp, J. H."Symmetric Dicyanobenzothiadiazole (DCBT) Dyes with a 1.5 eV Excited State Reduction Potential Range" RSC Adv. 2024,14, 6521. DOE [link]
122) [NIR/SWIR Materials] Ndaleh, D.; Meador, W. E.; Smith, C.; Friedman, H. C.; McGuire, M.; Caram, J. R.; Hammer, N. I.; Delcamp, J. H. "Near-infrared Emissive Indolizine Squaraine Fluorophores as Strong Molecular Viscosity Sensors" ChemPhotoChem 2023, DOI: 10.1002/cptc.202300212. NCS [link]
121) [Chromophores & Interfaces] Ndaleh, D.; Kaur, R.; Hogue, A.; Delcamp, J. H. "Benzothiophene-Based Cross-Conjugated Organic Dyes for High-Photocurrent Dye-Sensitized Solar Cells with Photocurrents up to 27 mA/cm2" ACS Appl. Energy Mater. 2023, 6, 10376. NCS [link]
120) [Chromophores & Interfaces] Curiac, C.; Lambert, E. C.; Hunt, L. A.; Roberts, M.; LaMore, A.; Peddapuram, A.; Cheema, H.; Hammer, N. I.; Delcamp, J. H. "Increasing Photoinduced Interfacial Charge Separation Lifetime through Control of the Twist Angle in the Donor Region of Carbazole-Based Dyes" J. Phys. Chem. C 2023, 127, 21474. DOE, T12 [link]
119) [Catalysis] Hunt, L. A.; Das, S.; Lamb, R. W.; Nugegoda, D.; Curiac, C.; Figgins, M. T.; Lambert, E. C.; Qu, F.; Hammer, N. I.; Delcamp, J. H.; Webster, C. E.; Papish, E. T. "Ruthenium (II) Complexes of CNC Pincers and Bipyridine in the Photocatalytic CO2 Reduction Reaction to CO Using Visible Light: Catalysis, Kinetics, and Computational Insights" ACS Catalysis 2023, 13, 5986. CAT2 [link]
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118) [NIR/SWIR Materials] Darlington, D. S.; Mahurin, A. N.; Kapusta, K.; Suh, E.; Smith, C.; Jarrett, E.; Chism, C. M.; Meador, W. E.; Kelly, Z. C.; Delcamp, J. H.; Zhao, Y.; Hammer, N. I.; Kariyawasam, C. S.; Somarathne, R. P.; Fitzkee, N. C.; Tanner, E. L. "Selective Near-Infrared Blood Detection Driven by Ionic Liquid–Dye–Albumin Nanointeractions" Langmuir 2023, 39, 10806. T12 [link]
117) [Chromophores & Interfaces] Meador, W. E.; Liyanage, N. P.; Watson, J.; Groenhout, K.; Delcamp, J. H. "Panchromatic NIR-Absorbing Sensitizers with a Thienopyrazine Auxiliary Acceptor for Dye-Sensitized Solar Cells" ACS Appl. Energy Mater. 2023, 6, 5416. NCS, REU4 [link]
116) [Chromophores & Interfaces] Li, Q. Y.; Kaur, R. K.; Meador, W. E.; Roy, J. K.; Leszczynski, J.; Delcamp, J. H. "Fused Double Donor Design with a Cross-Conjugated Dibenzosilin for Dye-Sensitized Solar Cells" ACS Omega 2023, 8, 29234. NCS, T12 [link]
115) [Chromophores & Interfaces] Santaloci, T. J.; Meador, W. E.; Wallace, A. M.; Valencia, E. M.; Rogers, B. N.; Delcamp, J. H.; Fortenberry, R. C. "An automated quantum chemistry-driven, experimental characterization for high PCE donor-π-acceptor NIR molecular dyes" Discovery 2023, Just Accepted. DOI: 10.1039/D3DD00023K. NCS, T12 [link]
114) [NIR/SWIR Materials] Saucier, M. A.; Smith, C.; Kruse, N. A.; Hammer, N. I.; Delcamp, J. H. "Acid-Triggered Switchable Near-Infrared/Shortwave Infrared Absorption and Emission of Indolizine-BODIPY Dyes" Molecules 2023, 28, 1287. T12 [link] >2000 Downloads
113) [Chromophores & Interfaces] Raithel, A. L.; Meador, W. E.; Kim, T.-Y.; Staples, R. J.; Delcamp, J. H.; Hamann, T. W. "Molecular Switch Cobalt Redox Shuttle with a Tunable Hexadentate Ligand" J. Am. Chem. Soc. 2023, 145, 1367-1377. NCS [link] >1000 Downloads
112) [NIR/SWIR Materials] Ranathunge, T. A.; Curiac, C.; Green, K. A.; Kolodziejczyk, W.; Hill, G.; Morgan, S.; Delcamp, J. H.; Watkins, D. L. "Heteroacene-Based Polymer with Fast-Switching Visible–Near Infrared Electrochromic Behavior" ACS Appl. Mater. Interfaces 2023, 240, DOI: 10.1021/acsami.2c21111. T12 [link]
111) [NIR/SWIR Materials] Singh, S.; Meador, W. E.; Pramanik, A.; Ray, P.; Delcamp, J. H.; Zhao, Y. "An indolizine squaraine-based water-soluble NIR dye for fluorescence imaging of multidrug-resistant bacteria and antibacterial/antibiofilm activity using the photothermal effect" J. Photochem. Photobio. B: Bio. 2023, 240, 112652. T12 [link]
110) [Chromophores & Interfaces] Dorris, A. L.; Watson, J.; Mosely, J. J.; Lambert, E. C.; Tschumper, G. S.; Delcamp, J. H.; Hammer, N. I. "Effects of Proaromaticity on Excited-State Lifetimes and Charge Separation in Near-Infrared Sensitizer Dyes in Solution and on TiO2" J. Phys. Chem. C 2023, 127, 649-659. NCS, AGEP [link] Supplementary Cover
109) [Strong Photooxidant] [Catalysis] Li, Q. Y.; Hunt, L. A.; Wijesinghe, K. H.; Curiac, C.; Williams, A.; Dass, A.; Hammer, N. I.; Delcamp, J. H. "Dicyanobenzothiadiazole (DCBT) Organic Dye as a Visible Light Absorbing Strong Photoinduced Oxidant with a 16 Microsecond Long-Lived Excited State" Adv. Energy Mater. 2023, 13, 2370008. DOE [link] Back Inside Cover
108) [Catalysis] Nugegoda, D.; Tzouras, N. V.; Nolan, S. P.; Delcamp, J. H. "N-Heterocyclic Carbene Gold Complexes in a Photocatalytic CO2 Reduction System" Inorg. Chem. 2022, 61, 18802. CAT2 [link]
107) [NIR/SWIR Materials] Chatterjee, S.; Shaik, A. K.; Wijesinghe, K. H.; Ndaleh, D.; Dass, A.; Hammer, N. I.; Delcamp, J. H. "Design and Synthesis of RhodIndolizine Dyes with Improved Stability and Shortwave Infrared Emission up to 1250 nm" J. Org. Chem. 2022, 87, 11319. T12 [link] >1000 Downloads
106) [NIR/SWIR Materials] Meador, W. E.; Kapusta, K.; Owolabi, I.; Autry, S. A.; Saloni, J.; Kolodziejczyk; W.; Hammer, N. I.; Flynt, A. S.; Hill, G. A.; Delcamp, J. H. "Ultra Bright Near-Infrared Sulfonate-Indolizine Cyanine- and Squaraine-Albumin Chaperones: Record Quantum Yields and Applications" ChemPhotoChem 2022, 6, e202200127. T12 [link] Cover
105) [Catalysis] Boudreaux, C. M.; Nugegoda, D.; Yao, W.; Le, N.; Frey, N. C.; Li, Q.; Qu, F.; Zeller, M.; Webster, C. E.; Delcamp, J. H.; Papish, E. T. "Low-Valent Cobalt(I) CNC Pincer Complexes as Catalysts for Light-Driven Carbon Dioxide Reduction" ACS Catal. 2022, 12, 8718. CAT2 [link] >2000 Downloads
104) [Chromophores & Interfaces] Roy, J. K.; Kaur, R.; Daniel, A.; Baumann, A.; Li, Q.; Delcamp, J. H.; Leszczynski, J. "Photophysical Properties of Donor–Acceptor−π Bridge–Acceptor Sensitizers with a Naphthobisthiadiazole Auxiliary Acceptor: Toward Longer-Wavelength Access in Dye-Sensitized Solar Cells" J. Phys. Chem. C 2022, 126, 11875. T12 [link]
103) [Chromophores & Interfaces] Devdass, A.; Watson, J.; Firestone, E.; Hamann, T. W.; Delcamp, J. H.; Jurss, J. W. "An Efficient Copper-Based Redox Shuttle Bearing a Hexadentate Polypyridyl Ligand for DSCs under Low-Light Conditions" ACS Appl. Energy Mater. 2022, 5, 5964. T12 [link]
102) [Chromophores & Interfaces] Nugegoda, D.; Bhattacharya, S.; Hunt, L. A.; Schwartz, S. J.; Turner, Z. H.; Hammer, N. I.; Jurss, J. W.; Delcamp, J. H. "Designing Self-Assembled Dye–Redox Shuttle Systems via Interfacial π-Stacking in Dye-Sensitized Solar Cells for Enhanced Low Light Power Conversion" Energy and Fuels. 2022, 36, 7075. T12, REU3 [link]
101) [Catalysis] Das, S.; Nugegoda, D.; Yao, W.; Qu, F.; Figgins, M. T.; Lamb, R. W.; Webster, C. E.; Delcamp, J. H.; Papish, E. T. "Sensitized and Self-Sensitized Photocatalytic Carbon Dioxide Reduction Under Visible Light with Ruthenium Catalysts Shows Enhancements with More Conjugated Pincer Ligands" Eur. J. Inorg. Chem. 2022, 2022, e202101016. CAT1, CAT2 [link]
100) [Chromophores & Interfaces] Nugegoda, D.; Hunt, L. A.; Devdass, A.; Cheema, H.; Fortenberry, R. C.; Jurss, J. W.; Hammer, N. I.; Delcamp, J. H. "Lewis Acid-Lewis Base Interactions Promote Fast Interfacial Electron Transfers with a Pyridine-Based Donor Dye in Dye-Sensitized Solar Cells" ACS Appl. Energy Mater. 2022, 5, 1516. T12, NCS [link]
99) [NIR/SWIR Materials] Chandrasiri, I.; Yaddehige, M. L.; Li, B.; Sun, Y.; Meador, W. E.; Dorris, A.; Zia, M. F.; Hammer, N. I.; Flynt, A.; Delcamp, J. H.; Davis, E.; Lippert, A.; Watkins, D. L. "Cross-linking Poly(caprolactone)-Polyamidoamine Linear Dendritic Block Copolymers for Theranostic Nanomedicine" ACS Appl. Polym. Mater. 2022, 4, 2972. T12 [link]
98) [Chromophores & Interfaces] Watson, J.; Rodrigues, R. R.; Delcamp, J. H. "Near-Infrared Unsymmetrical Squaraine Core-Based Sensitizers for Co-Sensitized High-Photocurrent Dye-Sensitized Solar Cells" Cell Rep. Phys. Sci. 2022, 3, 100701. NCS, AGEP [link]
97) [Chromophores & Interfaces] Hunt, L. A.; Rodrigues, R. R.; Foell, K.; Nugegoda, D.; Cheema, H.; Hammer, N. I.; Delcamp, J. H. "Preferential Direction of Electron Transfers at a Dye-Metal Oxide Interface with an Insulating Fluorinated Self-Assembled Monolayer and MgO" J. Phys. Chem. C 2021, 125, 25410. T2H, DOE, NCS [link]
96) [Chromophores & Interfaces] Munoz-García, A. B.; Benesperi, I.; Boschloo, G.; Concepcion, J. J.; Delcamp, J. H.; Gibson, E. A.; Meyer, G. J.; Pavone, M.; Pettersson, H.; Hagfeldt, A.; Freitag, M. "Dye-Sensitized Solar Cells Strike Back" Chem. Soc. Rev. 2021, 50, 12450. NCS [link] >200 Citations
95) [NIR/SWIR Materials] Ndaleh, D.; Smith, C.; Yaddehige, M. L.; Shaik, A. K.; Watkins, D. L.; Hammer, N. I.; Delcamp, J. H. "Shortwave Infrared Absorptive and Emissive Pentamethine-Bridged Indolizine Cyanine Dyes" J. Org. Chem. 2021, 86, 15376. T12 [link] >1000 Downloads
94) [Chromophores & Interfaces] Qi, Y.; Ndaleh, D.; Meador, M. E.; Delcamp, J. H.; Hill, G.; Pradhan, N. R.; Dai, Q. "Interface Passivation of Inverted Perovskite Solar Cells by Dye Molecules" ACS Appl. Energy Mater. 2021,4, 9525. T12 [link] >1000 Downloads
93) [NIR/SWIR Materials] Chatterjee, S.; Meador, M. E.; Smith, C.; Chandrasiri, I.; Zia, M. F.; Nguyen, J.; Dorris, A.; Flynt, A.; Watkins, D. L.; Hammer, N. I.; Delcamp, J. H. "SWIR emissive RosIndolizine dyes with nanoencapsulation in water soluble dendrimers" RSC Adv. 2021, 11, 27832. T12 [link]
92) [Chromophores & Interfaces] Curiac, C.; Hunt, L. A.; Sabuj, M. A.; Li, Q.; Baumann, A.; Cheema, H.; Zhang, Y.; Rai, N.; Hammer, N. I.; Delcamp, J. H. "Probing Interfacial Halogen-Bonding Effects with Halogenated Organic Dyes and a Lewis Base-Decorated Transition Metal-Based Redox Shuttle at a Metal Oxide Interface in Dye-Sensitized Solar Cells" J. Phys. Chem. C 2021, 125, 17647. T12 [link]
91) [NIR/SWIR Materials] Simms, B. L.; Ji, N.; Chandrasiri, I.; Zia, M. F.; Udemgba, C. S.; Kaur, R.; Delcamp, J. H.; Flynt, A.; Tan, C.; Watkins, D. L. "Physicochemical properties and bio-interfacial interactions of surface modified PDLLA-PAMAM linear dendritic block copolymers" J. Poly. Sci. 2021, 59, 2177. T12 [link]
90) [Chromophores & Interfaces] Curiac, C.; Rodrigues, R. R.; Watson, J.; Hunt, L. A.; Devdass, A.; Jurss, J. W.; Hammer, N. I.; Fortenberry, R. C.; Delcamp, J. H. "Iron Redox Shuttles with Wide Optical Gap Dyes for High Voltage Dye-Sensitized Solar Cells" ChemSusChem 2021, 14, 3084. DOE, T12 [link]
89) [Catalysis] Shirley, H. P.; Sexton, T. M.; Liyanage, N. P.; Perkins, M. A.; Autry, S. A.; McNamara, L. E.; Hammer, N. I.; Parkin, S.; Tschumper, G. S.; Delcamp, J. H. "Probing the Effects of Electron Deficient Aryl Substituents and a π-System Extended NHC Ring on the Photocatalytic CO2 Reduction Reaction with Re-pyNHC-aryl Complexes" ChemPhotoChem 2021, 5, 353. T2H, NCT [link]
88) [Chromophores & Interfaces] Cheema, H.; Watson, J.; Delcamp, J. H. "Integrating GaAs, Si, and Dye-Sensitized Solar Cells in Multijunction Devices and Probing Harsh Condition Behavior" ACS Appl. Electron. Mater. 2021, 3, 316. NCA, NCS [link]
87) [NIR Photodetector] Qi, Y.; Meador, W. E.; Xiong, J.; Abbaszadeh, M.; Delcamp, J. H.; Kundu, S.; Hill, G.; Dai, Q. "Structural, Optical, Photocatalytic, and Optoelectronic Properties of Zn2SnO4 Nanocrystals Prepared by Hydrothermal Method" Nanotechnology 2021, 32, 145702. T12 [link]
86) [Chromophores & Interfaces] Ndaleh, D. N. D.; Nugegoda, D.; Watson, J.; Cheema, H.; Delcamp, J. H. "Donor Group Influence on Dye-Sensitized Solar Cell Device Performances: Balancing Dye Loading and Donor Size" Dyes Pigm. 2021, 187, 109074. NCA, NCS [link]
85) [Chromophores & Interfaces] Wallace, A. M.; Curiac, C.; Delcamp, J. H.; Fortenberry, R. C. "Accurate Determination of the Onset Wavelength (λonset) in Optical Spectroscopy" J. Quant. Spectrosc. Radiat. Transf. 2021, 265, 107544. T12 [link]
84) [Chromophores & Interfaces] Watson, J.; Santaloci, T. J.; Cheema, H.; Fortenberry, R. C.; Delcamp, J. H. "Full Visible Spectrum Panchromatic Triple Donor Dye for Dye-Sensitized Solar Cells" J. Phys. Chem. C 2020, 124, 25211. NCA, NCS, T12 [link]
83) [NIR/SWIR Materials] Sparks, N. E.; Ranathunge, T. A.; Attanayake, N. H.; Brogdon, P.; Delcamp, J. H.; Rajapakse, R. M. G.; Watkins, D. L. "Electrochemical Copolymerization of Isoindigo‐Based Donor‐Acceptor Polymers with Intrinsically Enhanced Conductivity and Near‐Infrared‐II Activity" ChemElectroChem 2020, 7, 3752. T12 [link]
82) [Catalysis] Das, S.; Nugegoda, D.; Qu, F.; Boudreaux, C. M.; Burrow, P. E.; Figgins, M. T.; Lamb, R. W.; Webster, C. E.; Delcamp, J. H.; Papish, E. T. "Structure Function Relationships in Ruthenium Carbon Dioxide Reduction Catalysts with CNC Pincers Containing Donor Groups" Eur. J. Inorg. Chem. 2020, 2020, 2709. NCT [link] Special Issue Submission
81) [Catalysis] Shirley, H.; Figgins, M. T.; Boudreaux, C. M.; Liyanage, N. P.; Lamb, R. W.; Webster, C. E.; Papish, E. T.; Delcamp, J. H. "Impact of the Dissolved Anion on the Electrocatalytic Reduction of CO2 to CO with Ruthenium CNC Pincer Complexes" ChemCatChem 2020, 12, 4879. NCT [link] Special Issue Submission
80) [NIR Emissive] Chandrasiri, I.; Abebe, D. G.; Yaddehige, M. L.; Williams, J. S. D.; Zia, M. F.; Barker, A.; Dorris, A.; Parker, A.; Simms, B. L.; Le, N.; Gayton, J. N.; Hammer, N. I.; Delcamp, J. H.; Flynt, A.; Watkins, D. L. "Self-Assembling PCL-PAMAM Linear Dendritic Block Copolymers (LDBCs) for Bioimaging and Phototherapeutic Applications" ACS Appl. Bio Mater. 2020, 3, 5664. T12 [link] Supplementary Cover, >25 Citations
79) [Chromophores & Interfaces] Cheema, H.; Watson, J.; Delcamp, J. H. "Photon Management Strategies in SSM-DSCs: Realization of a >11% PCE Device with a 2.3 V Output" Solar Energy, 2020, 208, 747. NCA [link]
78) [Sensors] Gayton, J.; Li, Q.; Sanders, L.; Rodrigues, R. R.; Hill, G.; Delcamp, J. H. "Pyridyl CO2 Fixation Enabled by a Secondary Hydrogen Bonding Coordination Sphere" ACS Omega 2020, 5, 11687. T2A [link] >1000 Downloads
77) [Catalysis] Shirley, H.; Sexton, T. M.; Liyanage, N. P.; Palmer, C. Z.; McNamara, L. E.; Hammer, N. I.; Tschumper, G. S.; Delcamp, J. H. "Effect of “X” Ligands on the Photocatalytic Reduction of CO2 to CO with Re(pyridylNHC-CF3)(CO)3X Complexes" Eur. J. Inorg. Chem. 2020, 2020, 1844. NCT [link] Cover Feature
76) [Catalysis] Davis, S.; Nugegoda, D.; Tropp, J.; Azoulay, J. D.; Delcamp, J. H. "Molecular Au(I) Complexes in the Photosensitized Photocatalytic CO2 Reduction Reaction" MRS Commun. 2020, 10, 252. T2A [link] Invited Special Issue Submission Cover Article
75) [NIR/SWIR Materials] Ranathunge, T. A.; Ngo, D.; Karunarathna, D.; Attanayake, N. H.; Chandrasiri, I.; Brogdon, P.; Delcamp, J. H.; Rajapakse, R. M. G.; Watkins, D. L. "Designing Hierarchical Structures of Complex Electronically Conducting Organic Polymers via One-Step Electro-Polymerization" J. Mater. Chem. C 2020, 8, 5934. NCA [link]
74) [Chromophores & Interfaces] Cheema, H.; Watson, J.; Shinde, P. S.; Rodrigues, R. R.; Pan, S.; Delcamp, J. H. "Precious Metal-Free Solar-to-Fuel Generation: SSM-DSCs Powering Water Splitting with NanoCOT and NiMoZn Electrocatalysts" Chem. Commun. 2020, 56, 1559. DOE, T2H. [link]
73) [Chromophores & Interfaces] Daniel, A.; Delcamp, J. H. "Dye-Sensitized Solar Cells: A Brief Historical Perspective and Uses in Multijunction Devices" Submitted, Development of Solar Cells - Theory and Experiment, Spring Publishing, 2020, ISBN 978-3-030-69444-9. Part of the "Challenges and Advances in Computational Chemistry" series. DOE [link]
72) [NIR Emissive] Meador, W. E.; Autry, S. A.; Bessetti, R.; Gayton, J. G.; Flynt, A.; Hammer, N. I.; Delcamp, J. H. "Water Soluble NIR Absorbing and Emitting Indolizine Cyanine and Indolizine Squaraine Dyes for Biological Imaging" J. Org. Chem. 2020, 85, 4089. T12 [link] Supplementary Cover; >1000 Downloads; >25 Citations
71) [Chromophores & Interfaces] Baumann, A.; Curiac, C.; Delcamp, J. H. "Approaches to The Hagfeldt Donor and Use of Next Generation Bulky Donor Designs in Dye-Sensitized Solar Cell Dyes" ChemSusChem 2020,13, 2503. NCA [link] >25 Citations
70) [Sensors] Gayton, J.; Autry, S. A.; Kolodziejczyk, W.; Hill, G. A.; Hammer, N. I.; Delcamp, J. H. "Phosphate and Water Sensing with a Zinc Dipicolylamine-Based Charge Transfer Dye" ChemistrySelect 2020, 5, 1945. T2A, T2H [link]
69) [Chromophores & Interfaces] Rodrigues, R, R.; Lee, J. M.; Taylor, N. S.; Cheema, H.; Chen, L.; Fortenberry, R. C.; Delcamp, J. H.; Jurss, J. W. "Copper-Based Redox Shuttles Supported by Preorganized Tetradentate Ligands for Dye-Sensitized Solar Cells" Dalton Trans. 2020, 49, 343. T12 [link]
68) [Catalysis] Shirley, H.; Parkin, S. P.; Delcamp, J. H. "Photoinduced Generation of a Durable, High Turnover Frequency Thermal Proton Reduction Catalyst from a Manganese-Bipyridine Complex" Inorg. Chem. 2020, 59, 11266. NCT [link] Supplementary Cover
67) [Chromophores & Interfaces] Cheema, H.; Watson, J.; Peddapuram, A.; Delcamp, J. H. "A 25 mA/cm^2 Dye-Sensitized Solar Cell Based on a Near-Infrared-Absorbing Organic Dye and Application of the Device in SSM-DSCs" Chem. Commun. 2020, 56, 1741. NCA [link] >25 Citations
66) [Chromophores & Interfaces] Baumann, A.; Watson, J.; Delcamp, J. H. "Robust, Scalable Synthesis of the Bulky Hagfeldt Donor for Dye‐Sensitized Solar Cells" ChemSusChem 2020,13, 283. NCA [link] Cover Feature
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Assistant Professor Publications
65) [Chromophores & Interfaces] Cheema, H.; Delcamp, J. H. "SnO2 Transparent Printing Pastes from Powders for Photon Conversion in SnO2 Based Dye-Sensitized Solar Cells" Chem. Eur. J. 2019, 24, 14205. DOE [link]
64) [NIR Emissive] Rathnamalala, C. S. L.; Gayton, J. N.; Dorris, A. L.; Meador, W.; Hammer, N. I.; Delcamp, J. H.; Scott, C. N. "Donor-Acceptor-Donor NIR II Emissive Rhodindolizine Dye Synthesized by C-H Bond Functionalization" J. Org. Chem. 2019, 84, 13186. T12 [link] >3000 Downloads; >25 Citations
63) [NIR/SWIR Materials] Ranathunge, T. A.; Karunathilaka, D.; Ngo, D. T.; Attanayake, N. H.; Brogdon, P.; Delcamp, J. H.; Rajapakse, R. M. G.; Watkins, D. L. "Radically Accessing D-A Type Ambipolar Copolymeric Materials with Intrinsic Electrical Conductivity and Visible-Near Infrared Absorption via Electro-Copolymerization" Macromol. Chem. Phys. 2019, 1900289. T12 [link] Cover Article
62) [Chromophores & Interfaces] Rodrigues, R. R.; Peddapuram, A.; Dorris A. L.; Hammer, N. I.; Delcamp, J. H. "Thienopyrroledione-Based Photosensitizers as Strong Photoinduced Oxidants: Oxidation of Fe(bpy)3 2+ in a >1.3 V Dye-Sensitized Solar Cell" ACS Appl. Energy Mater. 2019, 2, 5547. DOE [link]
61) [Chromophores & Interfaces] Cheema, H.; Delcamp, J. H. "The Role of Anti-Reflective Coating CYTOP, Immersion Oil, and Sensitizer Selection in Fabricating a 2.3 V, 10% Power Conversion Efficiency SSM-DSC Device" Adv. Energy Mater. 2019, 1900162. T2H [link] [video abstract link]
60) [Catalysis] Das, S.; Rodrigues, R. R.; Lamb, R. W.; Boudreaux, C. M.; Qu, F.; Reinheimer, E.; Webster, C. E.; Delcamp, J. H.; Papish, E. T. "Highly Acitve Ruthenium CNC Pincer Photocatalysts for Visible Light Driven Carbon Dioxide Reduction" Inorg. Chem. 2019, 58, 8012. NCT/T2H [link] >3000 Downloads; >25 Citations
59) [Catalysis] Rodrigues, R. R.; Boudreaux, C. M.; Papish, E. T.; Delcamp, J. H. "Photocatalytic Reduction of CO2 to CO and Formate: Do Reaction Conditions or Ruthenium Catalysts Control Product Selectivity?" ACS Appl. Energy Mater. 2019, 2, 37. NCT/T2H [link] Invited Special Issue Submission >50 Citations, >3000 Downloads
58) [NIR Emissive] Gayton, J.; Autry, S. A.; Meador, W.; Parkin, S. P.; Hill, G. A.; Hammer, N. I.; Delcamp, J. H. "Indolizine-Cyanine Dyes: Near Infrared Emissive Cyanine Dyes with Increased Stokes Shifts" J. Org. Chem. 2019, 84, 687. T2A/T2H [link] >3000 Downloads; >25 Citations
57) [NIR Emissive] Gayton, J. N.; Autry, S.; Fortenberry, R. C.; Hammer, N. I.; Delcamp, J. H. "Counter Anion Effect on the Photophysical Properties of Emissive Indolizine-Cyanine Dyes in Solution and Solid State" Molecules, 2018, 23, 3051. T2A/T12/T2H [link] Invited Special Issue Submission; >25 Citations; >4000 Downloads
56) [Catalysis] Shirley, H.; Su, X.; Sanjanwala, H.; Talukdar, K.; Jurss, J. W.; Delcamp, J. H. "Durable Solar Powered Molecular Catalyst Systems for CO2 to CH4 Conversion" J. Am. Chem. Soc. 2019,141, 6617. T2H [link] >7000 Downloads; >100 citations
55) [Chromophores & Interfaces] Cheema, H.; Baumann, A.; Loya, E. K.; Brogdon, P.; McNamara, L. E.; Carpenter, C. A.; Hammer, N. I.; Mathew, S.; Risko, C.; Delcamp, J. H. "A NIR Absorbing Indolizine-Porphyrin Push-Pull Dye for Dye-Sensitized Solar Cells" ACS Appl. Mater. Interfaces 2019, 11, 16474. NCA/T2H [link] >1000 Downloads; >50 Citations
54) [Catalysis] Liyanage, N. P.; Yang, W.; Guertin, S.; Roy, S. S.; Carpenter, C. A.; Schmehl, R. H.; Delcamp, J. H.; Jurss, J. W. "Photochemical CO2 Reduction with Mononuclear and Dinuclear Rhenium Catalysts Bearing a Pendant Anthracene Chromophore" Chem. Commun. 2019, 55, 993. T2H [link] >25 Citations
53) [Chromophores & Interfaces] Steen, A. E.; Nguyen, S. T.; Ellington, T. L.; Balasubramaniam, S.; Chandrasiri, I.; Delcamp, J. H.; Tschumper, G. S.; Hammer, N. I.; Watkins, D. L. "Characterization of Furan- and Thiophene-containing Bispyridyl Oligomers via Spectroscopic, Electrochemical, and TD-DFT Methods" J. Phys. Chem. C 2019, 123, 15176. T2H [link]
52) [Chromophores & Interfaces] Peddapuram, A.; Cheema, H.; McNamara, L. E.; Zhang, Y.; Hammer, N. I.; Delcamp, J. H. "Quinoxaline-based Dual Donor, Dual Anchor Organic Dyes for Dye-Sensitized Solar Cells" Appl. Sci., 2018, 8, 1421. NCA/T2H [link] Invited Special Issue Submission; >3000 Downloads
51) [Catalysis] Rambukwella, M.; Sakthivel, N. A.; Delcamp, J. H.; Sementa, L.; Fortunelli, A.; Dass, A. "Ligand Structure Determines Nanoparticles' Atomic Structure, Metal-Ligand Interface and Properties" Front. Chem., 2018, 6, 330. T2H [link] >25 Citations; >5000 Downloads
50) [Chromophores & Interfaces] Baumann, A.; Cheema, H.; Sabuj, M. A.; McNamara, L. E.; Peddapuram, A.; Zhang, Y.; Nguyen, S. T.; Watkins, D. L.; Hammer, N. I.; Rai, N.; Delcamp, J. H. "Iodine Binding with Thiophene Versus Furan Based Dyes for DSCs" Phys. Chem. Chem. Phys. 2018, 20, 17859. NASA/T2H [link]
49) [Chromophores & Interfaces] Zhang, Y.; Cheema, H.; McNamara, L.; Hunt, L. A.; Hammer, N. I.; Delcamp, J. H. "Ullazine Donor-π bridge-Acceptor Organic Dyes for DSCs" Chem. Eur. J. 2018, 24, 5939. NCA/T2H [link]
48) [Catalysis] Carpenter, C. A.; Brogdon, P.; McNamara, L. E.; Tschumper, G. S.; Hammer, N. I.; Delcamp, J. H. "A Robust Pyridyl-NHC Ligated Rhenium Photocatalyst for CO2 Reduction in the Presence of Water and Oxygen" Inorganics 2018, 6, 22. T2H [link] Invited Special Issue Submission; >5000 Downloads
47) [Catalysis] Huckaba, A. J.; Shirley, H.; Lamb, R. W.; Guertin, S.; Autry, S.; Cheema, H.; Talukdar, K.; Jones, T.; Jurss, J. W.; Dass, A.; Hammer, N. I.; Schmehl, R. H.; Webster, C. E.; Delcamp, J. H. "A Mononuclear Tungsten Photocatalyst for H2 Production" ACS Catalysis 2018, 8, 4838. T2H [link] >2000 Downloads
46) [Chromophores & Interfaces] Rodrigues, R. R.; Cheema, H.; Delcamp, J. H. "A High Voltage Molecular Engineered Organic Sensitizer-Iron Redox Shuttle Pair: 1.4 V DSC and 3.2 V SSM-DSC Devices" Angew. Chem. Int. Ed. 2018, 57, 5472. T2H [link] >25 Citations
45) [Catalysis] Burks, D. B.; Davis, S.; Lamb, R. W.; Liu, X.; Rodrigues, R. R.; Liyanage, N. P.; Sun, Y.; Webster, C. E.; Delcamp, J. H.; Papish, E. T. "Nickel(II) pincer complexes demonstrate that the remote substituent controls catalytic carbon dioxide reduction" Chem. Commun. 2018, 54, 3819. T2H [link] Back Cover Selected; >25 Citations
44) [Chromophores & Interfaces] Zhang, Y.; Cheema, H.; London, A. E.; Morales, A.; Azoulay, J. D.; Delcamp, J. H. "Panchromatic Cross-Conjugated π-Bridge NIR Dyes for DSCs" Phys. Chem. Chem. Phys. 2018, 20, 2438. NCA/REU2 [link]
43) [Chromophores & Interfaces] Brogdon, P.; Cheema, H.; Delcamp, J. H. "NIR Absorbing Metal-Free Organic, Porphyrin, and Phthalocyanine Dyes for Panchromatic DSCs" ChemSusChem 2018, 11, 86. NCA [link] Invited Minireview Submission; >150 Citations
42) [Catalysis] Boudreaux, C. M.; Liyanage, N. P.; Shirley, H.; Siek, S.; Gerlach, D. L.; Qu, F.; Delcamp, J. H.; Papish, E. T. "Ruthenium(II) complexes of pyridinol and N-heterocyclic carbene derived pincers as robust photocatalysts for selective carbon dioxide reduction" Chem. Commun. 2017, 53, 11217. T2H [link] >25 Citations
41) [Chromophores & Interfaces] Cheema, H.; Peddapuram, A.; Adams, R. E.; McNamara, L.; Hunt, L. A.; Le, N.; Watkins, D. L.; Hammer, N. I.; Schmehl, R. H.; Delcamp, J. H. "Molecular Engineering of NIR Absorbing Thienopyrazine Double Donor Double Acceptor Organic Dyes for DSCs" J. Org. Chem. 2017, 82, 12038. NCA/T2H [link] >1000 Downloads, >25 Citations
40) [Chromophores & Interfaces] Brogdon, P.; Cheema, H.; Delcamp, J. H. "Low-Recombination Thieno[3,4-b]thiophene-based Photosensitzers for DSCs" ChemSusChem 2017, 10, 3624. NCA [link]
39) [Chromophores & Interfaces] Cheema, H.; Rodrigues, R. R.; Delcamp, J. H. "Sequential Series Multijunction Dye-Sensitized Solar Cells (SSM-DSCs): 4.7 Volts from a Single Illuminated Area" Energy Environ. Sci. 2017, 10, 1764. T2H [link] >25 Citations
38) [NIR Emissive] McNamara, L. E.; Rill, T. A.; Huckaba, A. J.; Ganeshraj, V.; Gayton, J.; Nelson, R. A.; Sharpe, E. A.; Dass, A.; Hammer, N. I.; Delcamp, J. H. "Indolizine-Squaraines: NIR Fluorescent Materials with Molecular Engineered Stokes Shifts" Chem. Eur. J. 2017, 23, 12494. T2H/HC [link] Frontispiece, >25 Citations
37) [Chromophores & Interfaces] Liyanage, N. P.; Cheema, H.; Baumann, A.; Zylstra, A. R.; Delcamp, J. H. "Effect of Donor Strength and Bulk on Thieno[3,4-b]pyrazine based Panchromatic Dyes in DSCs" ChemSusChem, 2017, 10, 2635. NCA/REU2 [link]
36) [NIR Emissive] Zhang, Y.; Autry, S. A.; McNamara, L. E.; Nguyen, S. T.; Le, N.; Brogdon, P.; Watkins, D. L.; Hammer, N. I.; Delcamp, J. H. "Near-infrared Fluorescent Thienothiadiazole Dyes with Large Stokes Shifts and High Photostability" J. Org. Chem. 2017, 82, 5597. T2H [link] >2000 Downloads, >25 Citations
35) [Chromophores & Interfaces] Peddapuram, A.; Cheema, H.; Adams, R. E.; Schmehl, R. H.; Delcamp, J. H. "A Stable Panchromatic Green Dual Acceptor, Dual Donor Organic Dye for Dye-Sensitized Solar Cells" J. Phys. Chem. C. 2017, 121, 8770. T2H/NCA [link] >25 Citations
34) [Catalysis] Cope, J. D.; Liyanage, N. P.; Kelley, P. J.; Denny, J. A.; Valente, E. J.; Webster, C. E.; Delcamp, J. H.; Hollis, T. K. "Electrocatalytic Reduction of CO2 with CCC-NHC Pincer Nickel Complexes" Chem. Commun. 2017, 53, 9442. T2H [link] >50 Citations
33) [Chromophores & Interfaces] Cheema, H.; Delcamp, J. H. "Harnessing Photovoltage: Effects of Film Thickness TiO2 Nanoparticle Size, MgO and Surface Capping with DSCs" ACS Appl. Mater. Interfaces 2017, 9, 3050. T2H [link]
32) [Chromophores & Interfaces] [NIR Emissive] Huckaba, A. J.; Yella, A.; McNamara, L. E.; Steen, A. E.; Murphy, J. S.; Carpenter, C. A.; Puneky, G. D.; Hammer, N. I.; Nazeeruddin, M. K.; Grätzel, M.; Delcamp, J. H. “Molecular Design Principles of Near-Infrared Absorbing and Emitting Indolizine Dyes” Chem. Eur. J. 2016, 22, 15536. NCA/T2H/HC/REU [link] >25 Citations
31) [Catalysis] Liyanage, N. P.; Dulaney, H. A.; Huckaba, A. J.; Jurss, J. W.; Delcamp, J. H. "Electrocatalytic Reduction of CO2 to CO With Re-Pyridyl-NHCs: Proton Source Influence on Rates and Product Selectivities" Inorg. Chem. 2016, 55, 6085. T2H [link]
>2000 Downloads; >50 Citations
30) [Chromophores & Interfaces] Huckaba, A. J.; Yella, A.; Brogdon, P.; Murphy, J. S.; Nazeeruddin, Md. K.; Grätzel, M.; Delcamp, J. H. "A Low Recombination Rate Indolizine Sensitizer for Dye Sensitized Solar Cells" Chem. Commun. 2016, 52, 8424. NCA/HC [link] >50 Citations
29) [Chromophores & Interfaces] Liyanage, N.; Yella, A.; Nazerruddin, Md. K.; Grätzel, M.; Delcamp, J. H. "Thieno[3,4-b]pyrazine as an Electron Deficient π-Bridge in D-A-π-A DSCs" ACS Appl. Mater. Interfaces 2016, 8, 5376. NCA [link] >50 Citations, >1000 Downloads
28) [Chromophores & Interfaces] Brogdon, P.; McNamara, L. E.; Peddapuram, A.; Hammer, N. I.; Delcamp, J. H. "Toward Tightly Bound Carboxylic Acid-Based Organic Dyes for DSCs: Relative TiO2 Binding Strengths of Benzoic Acid, Cyanoacrylic Acid, and Conjugated Double Carboxylic Acid Anchoring Dyes" Synth. Met. 2016, 222, 66. T2H/T1 [link] Invited Special Issue Submission
27) [Catalysis] Huckaba, A. J.; Sharpe, E. A.; Delcamp, J. H. "Photocatalytic Reduction of CO2 with Re-Pyridyl-NHCs" Inorg. Chem. 2016, 55, 682. T2H/HC [link] >4000 Downloads; >100 Citations
26) [NIR Emissive] McNamara, L. E.; Liyanage, N.; Peddapuram, A.; Murphy, J. S.; Delcamp, J. H.; Hammer, N. I. "Donor-Acceptor-Donor Thienopyrazines via Pd-Catalyzed C-H Activation as NIR Fluorescent Materials" J. Org. Chem. 2016, 81, 32. T1/T2H/HC [link] >50 Citations; >4000 Downloads
25) [Chromophores & Interfaces] Brogdon, P.; Giordano, F.; Puneky, G. A.; Dass, A.; Zakeeruddin, S. M.; Zazeeruddin, Md. K.; Grätzel, M.; Tschumper, G.; Delcamp, J. H. "A Computational and Experimental Study of Thieno[3,4-b]thiophene as a Proaromatic π-Bridge in DSCs" Chem. Eur. J. 2016, 22, 694. T1/NCA/HC [link] >25 Citations
24) [Catalysis] Hammer, N. I.; Sutton, S.; Delcamp, J. H.; Graham, J. D. "Photocatalytic Water Splitting and Carbon Dioxide Reduction" Handbook of Climate Change Mitigation and Adaptation 2015, Springer, DOI: 10.1007/978-1-4614-6431-0_46-2. SU
23) [Chromophores & Interfaces] Huckaba, A. J.; Giordano, F.; McNamara, L. E.; Dreux, K. M.; Hammer, N. I.; Tschumper, G. S.; Zakeeruddin, S. M.; Grätzel, M.; Nazeeruddin, Md. K.; Delcamp, J. H. "Indolizine-Based Donors as Organic Sensitizer Components for Dye-Sensitized Solar Cells" Adv. Energy Mater. 2015, 5, 1401629. T1 [link] >75 Citations
22) [Catalysis] Nimmala, P. Knoppe, S.; Jupally, V.; Delcamp, J.; Aikens, C.; Dass, A. "Au36(SPh)24 Nanomolecules: X-ray Crystal Structure, Optical Spectroscopy, Electrochemistry and Theoretical Analysis" J. Phys. Chem. B 2014, 118, 14157. SU [link] >75 Citations; >1000 downloads
21) [Catalysis] Jupally, V. R.; Dharmaratne, A. C.; Crasto, D.; Huckaba, A. J.; Kumara, C.; Nimmala, P. R.; Kothalawala, N.; Delcamp, J. H.; Dass, A. "Au137(SR)56 nanomolecules: composition, optical spectroscopy, electrochemistry and electrocatalytic reduction of CO2" Chem. Commun. 2014, 50, 9895. T1 [link] >50 Citations
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Postdoctoral Publications
20) Mathew, S.; Astani, N. A.; Curchod, B. F. E.; Delcamp, J. H.; Marszalek, M.; Frey, J.; Rothlisberger, U.; Nazeeruddin, M. K.; Grätzel, M. "Synthesis, Characterization and Ab Initio Investigation of a Panchromatic Ullazine–Porphyrin Photosensitizer for Dye-Sensitized Solar Cells" J. Mater. Chem. A 2016, 4, 2332. [link] >25 Citations
19) Giordano, A. J.; Pulvirenti, F.; Khan, T. M.; Fuentes-Hernandez, C.; Moudgil, K.; Delcamp, J. H.; Kippelen, B.; Barlow, S.; Marder, S. R. "Organometallic Dimers: Application to Work-Function Reduction of Conducting Oxides" ACS Appl. Mater. Interfaces 2015, 7, 4320. [link]
18) Mohapatra, S. K.; Fonari, A.; Risko, C.; Yesudas, K.; Moudgil, K.; Delcamp, J. H.; Timofeeva, T. V.; Brédas, J.-L.; Marder, S. R.; Barlow, S. "Dimers of Ninteen-Electron Sandwich Compounds: Crystal and Electronic Structures, and Comparison of Reducing Strengths" Chem. Eur. J. 2014, 20, 15385. [link] Back Cover; >25 Citations
17) Yum, J.-H.; Holcombe, T. W.; Kim, Y.; Rakstys, K.; Moehl, T.; Teuscher, J.; Delcamp, J. H.; Nazeeruddin, M. K.; Grätzel, M. "Blue-Coloured Highly Efficient Dye-Sensitized Solar Cells by Implementing the Diketopyrrolopyrrole Chromophore" Sci. Rep. 2013, 3, 2446. [link] >150 Citations
16) Delcamp, J. H.; Yella, A.; Holcombe, T. W.; Nazeeruddin, M. K.; Grätzel, M. “The Molecular Engineering of Organic Sensitizers for Solar Cell Applications” Angew. Chem. Int. Ed. 2013, 52, 376. [link] >100 Citations
15) Delcamp, J. H.; Shi, Y.; Yum, J.-H.; Sajoto, T.; Dell’Orto, E.; Barlow, S.; Nazeeruddin, M. K.; Marder, S. R.; Grätzel, M. “The Role of π-Bridges in High Efficiency DSCs Based on Unsymmetrical Squaraines” Chem. Eur. J. 2013, 19, 1819. [link] >75 Citations
14) Dualeh, A.; Humphrey-Baker, R.; Delcamp, J. H.; Nazeeruddin, M. K.; Grätzel, M. “Solid-State Dye-Sensitized Solar Cells Using a Novel Class of Ullazine Dyes as Sensitizers” Adv. Energy Mater. 2012, 3, 496. [link] >25 Citations
13) Dualeh, A.; Delcamp, J. H.; Nazeeruddin, M. K. and Grätzel, M. "Near-Infrared Sensitization of Solid-State Dye-Sensitized Solar Cells with a Squaraine Dye." Appl. Phys. Lett. 2012, 100, 173512. [link] >25 Citations
12) Delcamp, J. H.; Yella, A.; Nazeeruddin, M. K. and Grätzel, M. "Modulating Dye E(S+/S*) with Efficient Heterocyclic Nitrogen Containing Acceptors for DSCs." Chem. Commun. 2012, 48, 2295. [link] >25 Citations
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Graduate Publications
11) Delcamp, J. H. ; Gormisky, P. E. ; White, M. C. "Oxidative Heck Vinylation for the Synthesis of Complex Dienes and Polyenes." J. Am. Chem. Soc. 2013, 135, 8460. [link] >50 Citations; >5000 Downloads
10) Vermeulen, N. A.; Delcamp, J. H. and White, M. C. "Synthesis of Complex Allylic Esters via C-H Oxidation vs C-C Bond Formation." J. Am. Chem. Soc. 2010, 132, 11323. [link] >75 Citations; >4000 Downloads
9) Delcamp, J. H. and White, M. C. "1,2-Bis(phenylsulfinyl)ethane." e-EROS Encyclopedia of Reagents for Organic Chemistry 2009, DOI: 10.1002/047084289X.rn00971. [link]
8) Delcamp, J. H.; Brucks, A. P. and White, M. C. "A General and Highly Selective Chelate-Controlled Intermolecular Oxidative Heck Reaction." J. Am. Chem. Soc. 2008, 130, 11270. [link] >175 Citations; >6000 Downloads
7) Delcamp, J. H. and White, M. C. "Sequential Hydrocarbon Functionalization: Allylic C-H Oxidation/Vinylic C-H Arylation." J. Am. Chem. Soc. 2006, 128, 15076. [link] >175 Citations; >4000 Downloads
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Undergraduate Publications
6) Slinker, J. D.; Kim, J. S.; Flores-Torres, S.; Delcamp, J. H.; Abruna, H. D.; Friend, R. H. and Malliaras, G. G. "In Situ Identification of a Luminescence Quencher in an Organic Light-Emitting Device." J. Mat. Chem. 2007, 17, 76. [link] >25 Citations
5) Wolak, M. A.; Delcamp, J. H.; Landis, C. A.; Lane, P. A.; Anthony, J. E.; Kafafi, Z. "High- Performance Organic Light-Emitting Diodes Based on Dioxolane-Substituted Pentacene Derivatives." Adv. Funct. Mat. 2006, 16, 1943. [link] >100 Citations
4) Wolak, M. A.; Melinger, J. S.; Lane, P. A.; Palilis, L. C.; Landis, C. A.; Delcamp, J. H.; Anthony, J. E. and Kafafi, Z. H. "Photophysical Properties of Dioxolane-Substituted Pentacene Derivatives Dispersed in Tris(quinolin-8-olato)aluminum(III)." J. Phys. Chem. B 2006, 100, 7928. [link] >50 Citations
3) Atwood, D.A.; Delcamp, J. H. and Zaman, M. K. "Synthesis of 1,3-bis(4,5-dihydrothiazole)benzene." Main Group Chemistry 2006, 5, 137. [link]
2) Lane, P. A.; Wolak, M. A.; Melinger, J. S.; Williamson, R.; Palilis, L. C.; Delcamp, J. H.; Anthony, J. E. and Kafafi, Z. H. "Energy Transfer and Excitation Migration in a Doped Organic Semiconductor." Proc. SPIE-Int. Soc. Optic. Engin. 2005, IX, 5937. [link]
1) Payne, M. M.; Delcamp, J. H.; Parkin, S. R. and Anthony, J. E. "Robust, Soluble Pentacene Ethers." Org. Lett. 2004, 6, 1609. [link] >125 Citations; >1000 Downloads
Patents
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Associate Professor Patents
11) Darlington, D.; Meador, W. M.; Delcamp, J. H.; Tanner, E. "Ionic Liquid Encapsulation of NIR Dyes for the Improvement of Bloodstain Detection" US Provisional Patent Filed 2024.
10) Meador, W. M.; Ndaleh, D. N. D.; Chatterjee, S.; Delcamp, J. H. "Indolizine Dyes with Short Wavelength Infrared Absorption and Emission and Methods for Making and Using the Same" US Provisional Patent Filed 2021.
9) Scott, C.; Delcamp, J. H.; Hammer, N. I. “Design, Synthesis, and Photophysical Properties of a Novel NIR-II Dye for Biological Imaging and Optoelectronic Devices” US Provisional Patent Filed 2019.
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Assistant Professor Patents
8) Papish, E. T.; Delcamp, J. H. “Light Driven Metal Pincer Photocatalysts for Carbon Dioxide Reduction to Carbon Monoxide” US Patent Awarded 2021, US11103861.
7) Hollis, T. K.; Delcamp, J. H.; Webster, C. “Symmetrical CCC-NHC Pincer Metal Complexes and Symmetrical Bimetallic Complexes: Bio-activity, and Applications to Organic Transformations and Energy-related Catalytic Methods” US Patent Awarded 2021, US11084839.
6) Rodrigues, R. R.; Curiac, C.; Peddapuram, A.; Cheema, H.; Delcamp, J. H. “Dye-Sensitized Solar Cells” US Provisional Patent Filed 2017, serial number 62/537,208.
5) Huckaba, A.; Delcamp, J. H. "Indolizine-Based Dyes for Dye-Sensitized Solar Cells" US Patent Awarded 2020, US10562913. T1 [link]
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Postdoctoral Patents
4) Delcamp, J. H.; Grätzel, M.; Nazeeruddin, M. K. “Compounds for Electrochemical and/or Optoelectronic Devices” WO Patent 2013, 057538 A1
3) Yum, J.-H.; Delcamp, J. H.; Nazeeruddin, M. K.; Grätzel, M. “Novel Organic Dye and Preparation Thereof” Korean Patent 2011, Pending.
2) Mathew, S.; Delcamp, J. H.; Nazeeruddin, M. K.; Grätzel, M. “Porphyrin Ullazine Dye for DSSC” Eur. Patent 2012, Pending.
1) An, H.-C.; Jung, H.-J.; Bae, H.-G.; Park, C.-S.; Lee, C.-Y.; Grätzel, M.; Nazeeruddin, M. K.; Chenyi, Y.; Delcamp, J. H. “Novel Organic Dye and a Production Method Therefor” WO Patent 2012, 102544.
Dissertations
14) David Ndaleh, Ph.D. Dissertation: "MOLECULAR DONOR DESIGNS FOR SHORTWAVE INFRARED FLUORESCENT DYES AND DYE-SENSITIZED SOLAR CELLS APPLICATIONS" 2022, University of Mississippi [currently embargoed]
13) Dinesh Nugegoda, Ph.D. Dissertation: "DYE AND REDOX SHUTTLE INTERACTIONS TO PROMOTE FAST ELECTRON TRANSFER IN DYE-SENSITIZED SOLAR CELLS" 2022, University of Mississippi [currently embargoed]
12) Jonathon Watson, Ph.D. Dissertation: "ACHIEVING RECORD PHOTOCURRENT: STRATEGIES FOR HARVESTING AND UTILIZING LOW ENERGY PHOTONS IN ORGANIC DYE-SENSITIZED PHOTOVOLTAICS" 2022, University of Mississippi [currently embargoed]
11) Christine Curiac, Ph.D. Dissertation: "CONTROLLING RATE OF INTERFACIAL ELECTRON TRANSFERS VIA SYNTHETIC MODULATION OF ORGANIC CHROMOPHORES" 2022, University of Mississippi [currently embargoed]
10) Hunter Shirley, Ph.D. Dissertation: "Advancements Toward Sustainable Solar Fuel Production Utilizing Reductive Homogeneous Electro- and Photocatalysis" 2021, University of Mississippi, T2H, NCA [currently embargoed]
9) Jacqueline Gayton, Ph. D. Dissertation: "Cyanines, Squaraines, and Xanthene Based NIR Emissive Materials for Biological Imaging" 2020, University of Mississippi, T2A, T12 [currently embargoed]
8) Roberta Rodrigues, Ph.D. Dissertation: "High Voltage Dye-Sensitized Solar Cells and Molecular Photocatalysis for CO2 Reduction" 2019, University of Mississippi, NCA, T2H, DOE [currently embargoed]
7) Alexandra Baumann, Ph.D. Dissertation: "Effects of Halogen Bonding and NIR Tuning of Dyes for Dye-Sensitized Solar Cells" 2019, University of Mississippi, T12, T2H, REU2 [currently embargoed]
6) Shakeyia Davis, Masters Dissertation: "Ni and Au Transition Metal Complexes in the Photocatalytic CO2 Reduction Reaction" 2019, University of Mississippi, T2H, T2A [link]
5) Yanbing Zhang, Ph.D. Dissertation: "Near-Infrared High Efficiency Organic Dye Sensitized Solar Cells (DSCs) and Biological Fluorescent Imaging Dyes" 2019, University of Mississippi, NCA, T2H [link]
4) Adithya Peddapuram, Ph.D. Dissertation: "Organic Sensitizers for High Efficiency Dye-Sensitized Solar Cells" 2019, University of Mississippi, NCA, T2H [link]
3) Phillip Brogdon, Ph.D. Dissertation: "Near Infrared Absorbing Organic Dyes for Dye-Sensitized Solar Cells and Catalysts for Photocatalytic CO2 Reduction" 2018, University of Mississippi, NCA, T2H [currently embargoed]
2) Nalaka Liyanage, Ph.D. Dissertation: "Solar-to-Electric Dye-Sensitized Solar Cells (DSCs) with Thieno[3,4-B]pyrazine as an Electron Deficient π-Bridge and Solar-to-Fuel Catalytic Reduction of CO2 with Rhenium-Pyridyl-NHCs" 2018, University of Mississippi, NCA, T2H [currently embargoed]
1) Aron J. Huckaba, Ph.D. Dissertation: "Efficient Utilization of Solar Energy in Dye-Sensitized Solar Cells and in the Photocatalytic Reduction of Carbon Dioxide" 2015, University of Mississippi, T1 [link]